Desmear and electroless plating

Desmear and electroless plateIntroductionPrinted rope come on is drug ab roled in the electronic manufacturing for mechanical and galvanisingal support. It is electronic eithery bear ons the electric constituents using conductive traces, carved from bullshit covered onto a non-conductive veridical. Printed forget me drug board ar usually include copper and copper mixture squares that are coated to provide good mechanical and good conduction with former(a) devices in the assembly. Printed rounds board are utilise in all electronic equipments such(prenominal) as computer and mobile ph iodines and TV and communications equipment and satellite as well as in the control of gadgets in the factories, companies and other uses of the innumerablet th mmnt thr i trng inr in th dir fr jint bnding nd jint bnding-rigid and light B du t rtin mrkt tr. Th inrd thnlgil dmnd frm th ltt hndhld dvi ntining Digital mr nd nw richly TV rlutin rn wll th nwr mbil hn mn tht thr i urg in th rquirmnt fr jint bnding-rigid nl nd multi-jint bnding nl. Th nd t m rdu th nl ty nd t rdu th t f mnuftur, lwy h drivn th dvlmnt f nwr mthd f ring. (hlingr, 2002, 82)Thnilly th mtril invlvd in jint bnding / jint bnding-rigid PCB brd mnufturing gnrt lrg numbr f iu. n ky nrn i th lrg use vrin f mtril in n brd build-u wll th xti ntur f m f th mmnly ud mtril, water consupmition nd th inhrnt iu thy ri. (hlingr, 2002, 82)PCB are inexpensive, and stooge be highly reliable. They require oftentimes more design effort and higher initial cost than either wire-wrapped or come out-to-point constructed hitchs, but are much cheaper and faster for high-volume doing. Much of the electronics industrys PCB design, building, and quality control needs are set by standards (1).In 1885 before the appearance of electric circuit board and point to point production, plate of carton was utilize to connect the electric mop upices with wires and it was heavy and has big volume.Before printed circuit s point-to-point production was used for primary sample or teentsy production runs wire.Circuit boards were produced in the mid-1930, by Austrian inventor Paul Eisler. During World War II the United States produced them on a huge set for use in war radios. During this period the invention remained use in the military part, and until the end of the war it became available for commercial use.Basically, each electronic component has wire, and the PCB has holes cut for each wire of each component and the PCB carry and connects all the electric components. Printed circuit boards have copper tracks connecting the holes where the components are placed. They are designed oddly for each circuit and coiffe structure very easy. The coating on the get h former(a) of a circuit board are usually copper, created either by putting single lines automatically, or by coating the all board in copper and bear off away excess. The method of assembly is called through-hole formation. In fresh ci rcuit board production, it uses soldered in place on the board with very little hassle., this touch is usually be done by putting the still solder mixture, and baking the entire board to dissolve the components in place. Soldering could be done automatically by passing the board over wave, of dissolve solder in machine(1). In previous period to the creation of heighten-mount technology was in the mid-1960s, all circuit boards used wire to attach components to the board. But With the removing the wires from circuit boards, circuit boards have become lighter and more efficient to produce.Multiwire hop on was used during the 1980 and 1990s in that technique copper wire pre-insulated with a polyimide rosin is fixed in the insulation cover by a wiring machine.Multiwire Board allows through wiring so that the number of wires be in one horizontal surface signifi piletly increases, and consequently an high-density board crumb be manufactured with a smaller number of layers than an o rdinary printed wire boards. In addition, as Multiwire Board uses copper wire of a uniform diameter, it is superior in various electric characteristics such as providing stable characteristic impedance.Surface-mount technology appeared in the 1960s, and became storied in the early 1980s and became widely used by the mid 1990s. Components were mechanically redesigned to have small coat tabs or end caps that could be soldered straightway on to the PCB surface. Components became much smaller and component placement on some(prenominal) sides of the board became more common than with through-hole attach, allowing much higher circuit densities. Surface mounting provides itself well to a high degree of automation, reducing labour costs and incrassating the conduction and greatly increasing production and quality rates. Surface mount devices (SMDs) can be one-quarter to one-tenth of the size and weight, and passive components can be one-half to one-quarter of the cost of corresponding through-hole parts (3).The advantages of Surface mount technology arelittler components. Smallest is currently 0.5 x 0.25 mm.Has higher number of components and more connections per component. few holes should be activityed through abrasive boards.Easy automated assembly.Small mis downs in component placement are corrected automatically (the surface tension of the molten solder licks the component into alignment with the solder pads).Components can be putted on both sides of the circuit board.Lower resistance at the connection.Good mechanical performance under shake and vibration casts.SMT parts generally cost less than through-hole parts.Fewer unwanted RF signal effects in SMT parts when compared to guide parts, yielding better predictability of component characteristics.Faster assembly. Some placement machines are fit of placing more than 50,000 components per hour.And there are some DisadvantagesThermal capacity of the heat generator results in slow reaction whereby therma l profiles can be distorted. comm totally some type of error, either human or machine-generated, and includes the following goMelt solder and component removalResidual solder removal feeling of solder paste on PCB, direct component printing or dispensingPlacement and reflow of new component.Over the past few year, electronic products, and especially those which smoothen within the category of Consumer Electronics have been significantly reduced in physical size and weight. Products such as cellular telephones, lap-top computers, pagers, camcorders, have been reduced by as much as3/4 of their original introductory size and weight. The most significant contributing factor to this reduction has been the inclusion of fine pitch, Surface Mount (SM) components. The larger, thicker and heavier leaded Through-Hole (TH) packages.The Surface Mount (SM) was developed to give the customer with increased component density and performance over the larger Dual-Inline-Package (DIP). The SM also p rovides the similar high consistency. The Chip Scale (CSP) was developed to provide the customer with an additional increase in component performance and density over the SM . The CSP also provides the same high reliability as the DIP and SM packageComponents which are used in integrated circuits (chips), resistors, and capacitors can be soldered to the surface of the board or more commonly, attached by inserting their connecting pins or wires into holes drilled in the board. The increased component density and complexity required by the electronics industry demands increasing use of multilayer PCBs which whitethorn have three, four, or more intermediate layers of copper. Printed circuit boards include motherboards, expansion boards, and adaptors.Epoxy polymers are regularly used for electric circuit board manufacturing purposes, especially for built up layers and micro-vias in modern printed circuit boards. The sticking together of the plated metal layers to this polymer surface i s primary importance for the consistency of the internal connection. chemic treatment of the polymer surface changes the chemic and physical nature of the polymer. These results in specific groups of the polymer chain present on the surface and changes the roughness of the polymer layer. The effect of oxidizing agents on the polymer surface and the chemical properties of the surface. (4).Conducting layers are typically made of thin copper foil. Isolating layers are usually laminated together with epoxy resin. The board is usually coated with a solder cover that is green in color. Other colors that are normally available are blue, and red (2).A number of additional technologies may be applied to circuit boards for specialized usesCircuit boards, for example, are designed to be slightly flexible, allowing the circuit board to be placed in positions which would non otherwise be practical, or to be used in wire systems.Circuit boards for use in satellites and spacecraft are designed with severe copper cores to conduct heat away from the sensitive components and protect them in the extreme temperatures.Some circuit boards are designed with an internal conductive layer to carry motive to various components without the need of extra traces.Publications have documented the plating of nanoparticales of Cu (Copper plating) or Au on flexible polyimide ( Epoxy) by electroplatingCopper plating is the process in which a coating of copper is deposited on the item to be plated by using an electric current.Copper plating is a form of electroplating procedure which uses a thin covering of metal to the surface of a component or a frame of equipment in order to improve its material properties and conductivity electric circuit board and corrosion resistance and surface modification. Copper plating has an important use in another industries such as automotive, furniture, aerospace and ceramics. Important characteristics of the copper plating process reckon the type of proce ss, the copper plating solution and power consumption(5).Some important parameters must be take during copper platingKind of copper platingHow much necessary capacity of the copper plating systemHow much power will spending during the copper plating process.The electroless copper platting process involves of four basic operations cleaning, activation, acceleration, and deposition.Useful features of copper platingSupply good basecoat for nickel and chromium.Increase the conductivity and reduce the cost of productionSupply excellent electrical conductivity properties for applications such as electronics and telecommunications.Can be use as a sham in surface hardening procedures.Provide good lubrication in metal forming operations.Makes jewels look good.Although electroless copper has been successfully used for more than three decades, but trend difficulties in removing the electroless copper from the waste stream and the reason for that is The process is unsteady requiring stabiliz ing additives to avoid copper fall.Environmentally is not good produces complex agents, such as EDTAThe large number of process needs high water consumption.The electroless copper method has considerable percentage of water volume used. water use is high due to the essential rinsing required between nearly all of the process steps. Copper is found into the wastewater stream due to pull out from the cleaner conditioner, accelerator, and deposition baths process. Much of this copper is complexed with EDTA and needs special waste treatment considerations and that is not good for environmental. This waste must be hard-boiled during the process of manufacturing or shipped off-site, which adds another cost to using electroless copper(6).Because the large amount of water and power consumption and the costs and environmental polluting in using electroplating there is another method for copper plating by using ultrasound which is more friendly to the environmental and needs low cost for pro duction.Some papers refer to use ultrasonic in immersions plating, specially plating property via immersion plating techniques as a final finish in circuit board processing.The useful thing in ultrasound is reducing excessive electric current power and that reduce the cost of production at the larboard of the solder mask and copper circuit traces during the immersion silver plating process. Ultrasonics also used in cleaning printed circuit boards before plating.The another tip in printed circuit board manufacturing is cut process for printed circuit board the purpose of drilling is to produce holes inside the electric board for electronic components and all the electronic components be on these holes.Holes are drilled through the cover so that component can be inserted and then fixed firmly in place. There are generally two types of components that are attachable to the circuit board such as resistors, transistors, which are attached to the circuit board by putting each of the legs of components through a hole in the board. In a printed circuit board which uses surface mount technology, components are placed promptly to the cover on the surface. Each set hole in the printed circuit board is planned to receive a exacting component. Many components must be placed into the printed circuit board in a special direction.The simplest printed circuit boards, wires must be printed on more than one surface of fiber nut to let all the component interconnections. Each surface containing printed wires is called a layer or film. Simple printed circuit board which requires only two layers, only one piece of fiberglass is required because wires can be printed on each sides. Some printed circuit board has several layers, individual circuit boards are manufactured independently and then coated together to produce one multi layer circuit board. To connect wires on two or more layers small holes called vias are drilled through the wires and fiberglass board at the point whe re the wires on the different layers cross. The interior surface of these holes is coated with metal so that electric current can flow through the vias. Some more complex computer circuit boards have more than 20 layers.The printed circuit board has green colour because strawman of thin sheets of green plastic on the both sides and without that the printed circuit board will appears in pale yellow colour. Called solder masks, these sheets cover all metal other than the component covers and holes.Electric circuit components are manufactured with covered metal pins which are used to fix them to the printed circuit board both mechanically and electrically so electric current can pass between them. The soldering process, which provides mechanical bond and a very good electrical connection, is used to connect the components to the printed circuit board. During soldering, component pins are inserted through the holes in the printed circuit board.A multilayer printed circuit board which c an be interlayer connection with low resistance. The multilayer printed circuit board have a conductive design on one face and without connection hole on the other face, for applying the conductive design to outside a second substratum having a conductive design formed on a face opposed to the other face of first substrate and a conductive coke on the conductive design integrally. The first substrate and the second substrate are integrated by engaging the bump of the second substrate with the connection hole of the first substrate and by intervening a conductive cement between the bumps and the conductive pattern undefended to outside from the connection holes(7).Some papers refer to use laser drilling to create holes during the manufacturing process for printed circuit board and that is also possible with controlled drilling by using computer program software or by pre-drilling the individual sheets of the printed circuit board before production, in order to produce holes which c onnect only some of the copper covers, rather than let them to go through the all board. These holes are called blind vias when they connect an internal copper layer to an outmost layer.Methods to Make Printed Circuits BoardThr r hndful of wy vilbl to produce PB. Thy yild rult of diffrnt quliti, whr th qulity m to b invrly proportionl to th mount of m you mk (in mot ), nd mount of mony you pnd (in ll ). Ill tlk composition bout h, nd thn ompr thm ll t th bottom of th pg.ny pro tht involv mking bord will hv numbr of tp in ommon. t high lvl and the steps includeProur br bord made from Epoxy resin (otd with thin lyr of oppr on ithr on or both id) by using electroplating with copper. Mot mthod will u plin bord photolithogrphy rquir on otd with pil light-nitiv hmiland rp off ny burr long th bord dg (you wnt flt oppr urf nd ln it wll to rmov oxidtion nd fingr oil, follow up with dnturd lohol to rmov ny oil or gr, nd finih by buffing with vry ln towl. From thi point on, youll wn t to hndl your bord only by th dg to void gtting fingr oil on it.Digning the iruit board. Dpnding on how is the tul production for th bord, the dign will tk on of numbr of diffrnt form hnd-drwn t of lin on ppr, omputr-drwn digrm.Trnfr the dird oppr tr to th pltd id() on the bord th trnfrrd tr r ritnt to the thing liquid. Mot bord prodution mthod diffr only in how thy omplih thi tp. If the board needs gnrting dign vi omputr, that will needs to put om thought into whih wy the faces on the printd dign will be.th th bord which was trd, The thnt hmil rmov ll non-mkd oppr ftr it don and then give th bord good wh undr running wtr to rmov ll tr of th thnt. In mot , th thnt will ithr b Frri hlorid or mmonium Prulft (Frri hlorid i mor populr). Th r vilbl in both liquid (i.., prmixd) nd powdr form th powdr i gnrlly quit bit hpr, but rquir r whn mixing.lo not tht thing prod ftr with wrmr thnt, nd gittion. long with ving you tim, ft thing lo produ bttr dg qulity nd onitnt lin width, o ft i good in thi tp. Pr-ht Frri hlorid thnt in th mirowv for 40 ondut th bord to finl iz nd hp, nd drill hol in th bord for omponnt ld. Th nd to b vry mll hol (bout 0.8 mm).rfully rub off th mk (with fin tl wool undr running wtr), nd popult th bord (i.., oldr with the omponnt). And only the mask hould rub off th whn the soldering is rdy, th oppr tr oxidiz quikly within fw dy.ftr th bord i popultd (i.., ll th omponnt hv bn oldrd on), quik ot of pry polyurthn vrnih, thi kp th hiny oppr tr looking hiny, nd provid bit of inultion gint hort du to try wir bruhing up gint th bord.ltrl rEltrl r h bn ufully ud fr mr thn thr dd, limit n rtr xur t frmldhyd nd diffiulti in rmving th ltrl r frm th wt trm ud mnufturr t k other methods. Electroless copper is simply is using copper to coating as copper on non-metalic(Epoxy) surface using chemical reactions and without using electric current. . It was used to make non-metallic surface conductive or has poor conductivity and that will provide electric al connection to the devices. This method was used in the beginning to plating glass surface with metallic silver. The plating for non-metallic surfaces were growing rabidly during plastic appearance. The plastic was used after that as non-metallic surface (Epoxy). The plastic material in the beginning was print chemically by using chromic acid sulfuric acid mixture.The disadvantageous and advantagous for electroless plating compaired with other electro plating (Coombs, 2007)U f frmldhyd rduing gnt.Th r i inhrntly untbl, rquiring tbilizing dditiv t vid r riittin.nvirnmntlly undirbl mlxing gnt, uh DT, r ud.Th lrg numbr f r nd rin tnk u high wtr numtin.Th ltrl r r nit f fur bi rtin lning, tivtin, lrtin, nd ditin (Coombs, 2007).ntnt thing rt. Th thing rt i dndnt n tmrtur nd hydrgnrxid nntrtin, nt th r nntrtin.iml wt trtmnt. N hltr r rnt in ulfuri-rxid mirthnt. high r ity f 3 t 4 un/glln.ffiint r rvry. r ulft rvry i uully 90-95%The electroless has steps which is includes below desc ribed stepsStep 1 The Cleaner-. alkalic permanganate to cleaning and to remove soil and condition holes.Step 2 Acid etching to remove copper surface contaminants.Step 3 Sulfuric Acid. utilize to remove microetch.Step 4 Pre-dip. Used to stay chemical balance for the next treatment step.Step 5 Catalysis. Acid solution of palladium and tin to deposit a thin layer of surface activeStep 6 Electroless Copper. Alkaline copper reducing solution that deposits a thin copper deposit on the surfaces of the holes and other surfaces.Th ltrl r r nit f fur bi rtin lning, tivtin, lrtin, nd ditin (Coombs, 2007). n nti-trnih bth i mmn ftr ditin. Virtully ll h urh ri f rritry hmitri frm ingl vndr tht r ud th ingrdint fr th vrl r bth in th ltrl r r lin.lning. Th lning gmnt bgin with lnr-nditinr dignd t rmv rgni nd nditin (in thi wll) th hl brrl fr th ubqunt utk f tlyt, fllwd by mirth t. Th lnr-nditinr r tyilly rritry frmultin, nd mtly nit f mmn lklin lutin. mirth t n b fund n th ltrl lin, xid li n, ttrn lt lin nd with hmil lning if tht i th lning mthd ud. Thr hmitry ltrntiv r vilbl. ulfuri id-hydrgn rxid (niting f 5% ulfuri id nd 1% t 3% rxid) i mt mmn, fllwd by ulfuri id-tium (r dium) rulft (5% ulfuri, 8 t 16 un/ glln rulft) nd mmnium rulft. In h , th mirth bth i fllwd by ulfuri id di, whih rv t rmv ny rmining xidizr. but 40 mirinh f r r thd fr th mking hl ndutiv r. Bd n 3-4 un r rrying ity, rximtly 0.0183 glln f mirth r ud r qur ft f rdut run. Thi figur d nt inlud ny lutin tht my b drggd ut whn th nl r mvd t th nxt tnk. Th ulfuri-rxid ltrntiv h m ttrtiv wt trtmnt nd rfrmn ftur (Coombs 2007)Gold was also used for electroless platting and the gold was used as nanoparticles with silica to make the silica surface conductive and that is depends on the chemical properties between the silica surface and the gold nanoparticles the connection between them depend on the charge for silver and the gold nanoparticles. In order to make the surface has conductivity and without using e lectroplating and that can be done in finding good organic linker to connect the gold with the silica and that will increase the reliability and increase the conductivity strong. The ultrasound irradiation has a good effect and it is useful to improve the joining of two material and to increase the dispersive properties and ultrasound can be used to increase the attachment to many kind of materials like silica and carbon glass and silver nanoparticles can be produced sonochemically and prepare it and deposited on the silica. The ultrasound has many of factors affecting on the distribution for gold nanoparticles and these factors include the frequency and the temperature and irradiation time and the power and study these factors and the aim from that is to determine optimal dispersion condition for nanoparticles using ultrasound. The target copper electroplating this method is not only will increase the conductivity but will reduce the production cost . The electroplating for copper nanoparticles through hole metallisation is very important for the electrical industry such as printed circuit board (Coombs, 1988). n nti-trnih bth i mmn ftr ditin. Virtully ll h urh ri f rritry hmitri frm ingl vndr tht r ud th ingrdint fr th vrl r bth in th ltrl r r linThe metallization for PCB can be done by electroplating and electroless plating or electrolytic plating.Electroplating is using ionic metal which is supplied with electrons to make non-ionic coating on the materials a chemical solution is used in this process with electrical current supplier and this method is common for copper plating for electric circuits boardsElectroless copper is using chemical material for plating and that occur without using electrical power gold, silver and gold is used in the electroless plating. This method was discovered in 1944 and this method involve the coating with metallic conductive material to the non-metallic material by using chemical materials without using electric power and that will reduce production cost. Electroplating was used for non-metallic material such as plastics (Epoxy) which are used in the printed circuits boardsDmrDesmear is the process which is used to remove smeared epoxy-resin and this process involves three steps (Solvent swell, Permanganate and nutulaizer) and that is important to ensure electrical conductivity for the layer after deposition process. Most electric Circuits boards material need removing to the drill smear and resin texturing preceding to metallization. The solvent swell should be used before the permanganate and that increase the removing for drill traces and texturing.Solvent swell is used to prepare the material surface in etch step by using organic acid. Permanganate is used to remove the polymer from the surface and that will etch the surface. Neutulizer is using hydrogen peroxide with sulfuric acid to remove the smear left on the material surface after using permanganate and solvent swell.hmitry f Dmr ltingDesm ear process includs chemical reaction which are oxidation reactions by using alkaline permanganate ( Potassium or sodium) and this step called solvent swell. Alkaline permanganate is highly oxidizing medium. In the oxidation process for permanganate the permanganate reduced to manganate and manganate and then react with water to produce insoluble atomic number 25 dioxide in the reaction below (Deckert, 1984)MnO4- + 2H2O + 3e- MnO2 + 4OH-In the neutralization process includes removing the surface to ensure that all manganese dioxide are removed from the board surface and through holes. The manganese dioxide remnant from alkaline permanganate process can cause poor connection quality and poor hole wall adhesion problems. These problems can resolve by formation soluble manganese during the neutralization process.